Real Oviedo have not won any of their five LaLiga matches against Villarreal (D2 L3), with Villarreal being the opponent against whom the Asturian side have played the most games in the competition without winning any.

In all competitions, Villarreal CF have avoided defeat in three of their four away games against Real Oviedo (W1 D2 L1), although they only managed to score in the match they won (3-1 in LaLiga in February 2001).